n.乙炔化合物
Cuprous acetylide takes the form of a russet or reddish-brown powder, insoluble in water and in the majority of organic solvents. 乙炔亚铜是黄褐色的红棕色的粉末,不溶于水和大多数有机溶剂。
Synthesis of carbyne by oxidation polycondensation of dicopper acetylide with Cu~(1+) and Cu~(2+) coordination as catalysis was studied by FTIR, DSC and SEM. 用FTIR、DSC及SEM对Cu+和Cu2+的催化氧化乙炔化物缩聚合成线型碳进行了研究,结果表明:Cu2+发挥了关键的作用;
Based on the experiment, we optimized the conditions of prepare linear carbon by two-steps method of oxidative coupling of copper acetylide, it spend only several hours to get the product, and the quantity of product is stable. 通过大量的实验,我们对炔烃氧化缩聚两步法合成线型碳的条件做了不小的改进,制备过程只需几小时,大大缩短了合成周期,在定量方面,使得合成条件更加明确,合成的产品质量也十分稳定;
Keywords hydrocarbon with end alkynyl active hydrogen cuprous acetylide; 关键词末端炔烃;活泼氢;乙炔亚铜;
Keywords Alkynyl;coprous acetylid;transformer oil spectrophotometry; 炔烃;乙炔亚铜;分光光度法;配电变压器油;